Title has, I am certain of it, been done before. I finally decided to go and draw Chrysalis for real though! I'm not sure if I'll like this as much as I do now tomorrow, but well here she is, the Queen of the Changelings!
It was done completely digitally in Photoshop Elements 10, using a chalk brush under the dry media default brush set, if I remember correctly? The lines are with the hard round, and the hair was painted with a speckle brush I made myself. And with a pressure sensitive tablet.